Gennady Zaikov

Yuri Monakov

Natalia Sigaeva

Vadim Urazbaev

The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are di

Multiplicity: Stereospecific and Kinetic Heterogeneity

Active Sites of Polymerization

Mukbaniani

The demand for organosilicon elastomers used in the production of thermally resistant rubbers and organosilicon polymers for making non-metal composite materials is increasing from year to year.This monograph presents a discussion on the methods used for synthesizing and studying properties of newly designed organosilicon polymers, namely organosil

Cyclolinear Organosilicon Copolymers: Synthesis, Properties, Application

Elena Burlakova

Alexander Evgen'evich Shilov

Sergey Dmitrievich Varfolomeev

The volume is devoted to the problem of chemical kinetics on modern level. The book includes information on chemical physics of nanocomposites, degradation, stabilization and flammability of polymeric materials as well as free radical mechanism of oxidation of organic compounds, thermostability, mechanism of action of catalytical systems and inhibi

Chemical kinetics

Sabu Thomas

Valsaraj

This book is a collection of technical papers focusing on the preparation, characterization and application of polymer nanocomposites. The various chapters in the book are written by prominent researchers from industry, academia, and government/private research laboratories across the globe. Different techniques adopted for the preparation of nanocomposites, their methods of characterization and their applications are discussed. The main objective of this book is to summarize in a fairly comprehensive manner many of the recent technical accomplishments in the area of polymer nanocomposites. The book is intended to serve as a one stop reference resource for important research accomplishments in the area of polymer nanocomposites.

Recent Advances in Polymer Nanocomposites

Levashova

The book generally shows the interrelation between allyl unit structure of the initial ester and composition and structure of its products. The first part studies the pathways of chemical regrouping in chlorallylaryl and bisarylallyl esters using quantum-chemical calculations. Energy parameters, structural features and electron structure of intermediates and transition states are also discussed. Simple and regioselective methods for compound synthesis inaccessible in other production techniques are developed. For the first time, new four- and eight-term nitrogen-containing heterocyclic compounds were produced by aniline alkenylation technique. In 0.05% aqueous solution these compounds displayed 100% activity in suppression of sulfate-reducing bacterium growth. Two new classes of complex action preparations designed for the oil production rate increase were obtained by heterocyclic amine alkenylation. Production methods for N-alkenyl ammonium salts derived from hexamethylene tetramine are developed and introduced into production, and compounds are used on oil fields. In the second part production methods of new mono-, di-, tri- and tetra-tert-butyl hexamethylene tetramine chlorides are discussed. These compounds fully suppress sulfate-reducing bacterium growth already in 200 – 500 mg/l concentration. A universal technology deriving bactericides and sulfide corrosion inhibitors for metals from methallyl chloride is developed. It also gives a method for organochlorine waste and methallyl chloride production wastewater management, safe for the environment.

Transformations of Allyl-Substituted and Aryl-Allyl Esters and Their Corresponding Amines

Meera

This book examines the current state of the art, new challenges, opportunities, and applications in the area of polymer nanocomposites. Special attention has been paid to the processing-morphology-structure-property relationship of the system. Various unresolved issues and new challenges in the field of polymer nanocompostes are discussed. The influence of preparation techniques (processing) on the generation of morphologies and the dependence of these morphologies on the properties of the system are treated in detail. This book also illustrates different techniques used for the characterization of polymer nanocomposites. The handpicked selection of topics and expert contributors across the globe make this survey an outstanding resource reference for anyone involved in the field of polymer nanocompostes for advanced technologies.

Recent Advances in Polymer Nanocomposites: Synthesis and Characterisation

Kozlov

The basic problem of polymer physics is obtaining a ‘structure-propertiesa correlations for their future application for practical purposes. However, these cannot be obtained without the development of a quantitative model of the polymer structure.This problem has been actively investigated during the last 45 years, which resulted in obtaining a

Structure of the Polymer Amorphous State

Lyudmila Shibryaeva

Anatoly Popov

To identify the specific features of the kinetics of oxidation of polymer mixtures, determine the key structural elements, and create a model that can describe the mechanism of thermal oxidation of polymer mixtures, it is necessary to determine the relation between the initial structure of a polymer mixture, structural rearrangements associated with oxidation and the kinetics of the process. The aim of this book is to elucidate the complicated problem concerning the connection between the structure and mechanism of oxidation of heterogeneous and heterophase polymer systems. The material presented in this book concerns the specific features of the kinetics of oxidation and those of the structure of polymer systems. The book deals with an analysis of the key factors that can affect principally the mechanism of thermal oxidation of polymer mixtures, determines the role of the phase morphology, structure of components, and the interface layer (or boundary) in the kinetics of oxidation of heterophase system by an example of mixtures of polyolefines. Along with the kinetics of oxidation of heterophase systems, problems of investigation of their structural parameters in the oxidized state are considered. With this aim, the material presented in the book concerns not only the mechanism of oxidation of polymer mixtures but also homopolymers of diverse morphology and model systems.

Gennady Zaikov

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